how do I produce unique random numbers as an array in Python?

I have an array with size (4,4) that can have values 0 and 1, so I can have 65536 different arrays. I need to produce all these arrays without repeating. I use wt_random=np.random.randint(2, size=(65536,4,4)) but I am worried they are not unique. could you please tell me this code is correct or not and what should I do to produce all possible arrays? Thank you.